• Title of article

    Synthesis of Bis(Phenoxyimine)Zirconium Dichloride Complexes Containing Bromo, lodo, or Alkynyl Substituted Phenoxyimine Ligands as Catalyst Precursors for the Polymerization of Ethylene

  • Author/Authors

    Gorl, Christian Universltat Bayreuth - Laboratorium fur Anorganische Chemie, Germany , Alt, Helmut G. Universltat Bayreuth - Laboratorium fur Anorganische Chemie, Germany

  • Pages
    23
  • From page
    245
  • To page
    267
  • Abstract
    A series of 23 bis(phenoxyimine)zirconium complexes (FI complexes) containing halogen or alkynyl substituents in their ligand frameworks was synthesized and characterized. After activation with methylalumoxane (MAO), these catalysts polymerize ethylene with good activities. Halogen or alkynyl functions may be used as anchoring points in subsequent Sonogashira type coupling reactions.
  • Keywords
    Phenoxyimine , Bis(phenoxyimine) zirconium complexes , Salicylaldehydes , Ethylene polymerization
  • Journal title
    Jordan Journal of Chemistry
  • Serial Year
    2008
  • Journal title
    Jordan Journal of Chemistry
  • Record number

    2682943

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2682943