Title of article
Synthesis, Spectroscopic and Antibacterial Studies of N(2-amino phenyl)-N-((pyridine-2-yl)methyl)Benzene-1,2-Diamine Complexes
Author/Authors
Naji, Shaymaa H Department of Chemistry - College of Education - Ibn- Al- Haitham - University of Baghdad, Baghdad-Iraq
Pages
8
From page
59
To page
66
Abstract
N(2-amino phenyl)-N-((pyridine-2-yl)methyl) benzene-1,2-diamine (L) was prepared from the reaction of ortho amino phyenylthiol with N(2-amino methyl pyridyl) phenyl diamine in mole ratio (1:1). It was characterized by elemental analysis (CHN),2H, 21C-NMR, IR and Uv-Vis. The complexes of the bivalent inos (Co (II), Ni (II), Cu (II), Pd (II), Cd (II) and Hg (II)) and the trivalent (Cr (III)) have been prepared and characterized too. The structural were established by elemental analysis (CHN), IR, Uv-Vis spectra, conductivity measurements, atomic absorption and magnetic susceptibility. The complexes showed characteristic behavior of octahedral geometry around the metal ions except with Cu and Pd complexes showed square planer, other parameters for complexes were estimated. The study of biological activity of the ligand (L) and its metal complexes showed various activity toward staphylococcus aureus and E. coli
Keywords
Synthesis , characterization , complexes , benzene , pyridine , biological study
Journal title
Al-Nahrain Journal Of Science
Serial Year
2014
Journal title
Al-Nahrain Journal Of Science
Record number
2683852
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