Title of article :
Synthesis and Characterization of Some New Metals Complexes of [N-(4-Nitrobenzoyl Amino)-Thioxomethyl] Phenylalanine
Author/Authors :
sarhan, basima m. university of baghdad - ibn- al-haitham education college - department of chemistry, Iraq , al-karboly, mohammed a. university of al-anbar - college of education for pure sciences - department of chemistry, Iraq , zaidan, dena h. university of al-anbar - college of education for pure sciences - department of chemistry, Iraq
Abstract :
A new ligand [N-(4-nitrobenzoylamino)-thioxomethyl] phenylalanine is synthesized by reaction of 4-nitrobenzoyl isothiocyanate with phenylalanine (1:1). It is characterized by micro elemental analysis (C.H.N.S.), FT-IR, (UV-Vis) and 1H and 13CNMR spectra. Some metals ions complexes of this ligand were prepared and characterized by FT-IR, UV-Visible spectra, conductivity measurements, magnetic susceptibility and atomic absorption. From results obtained, the following formula [M(NBA)2] where M2+ = Mn, Co, Ni, Cu, Zn, Pd, Cd and Hg, the proposed molecular structure for these complexes as tetrahedral geometry, except copper and palladium complexes are have square planer geometry
Keywords :
Phenylalanine , 4 , Nitrobenzoylisothiocyanate , Metal complexes.
Journal title :
Baghdad Science Journal
Journal title :
Baghdad Science Journal
