Title of article
A Combined Theoretical and Experimental Approach to 2,3,2,3Tetrahydro-1H,1H-[2,2]Biindenyl
Author/Authors
Hussain, Zakir Max-Planck-Institut für Bioanorganische Chemie, Germany , Hopf, Henning Technische Universität Braunschweig - Institut für Organische Chemie, Germany , Oeser, Thomas Organisch-Chemisches Institut der Universität Heidelberg, Heidelberg , Grunenberg, Joerg Technische Universität Braunschweig - Institut für Organische Chemie, Germany
From page
539
To page
543
Abstract
Synthesis of 2,3,2 ,3 -tetrahydro-1H,1 H-[2,2 ]biindenyl 2 from the dimerization reaction of indene with lithium naphthalenide was carried out and we here report its single crystal X-ray structure. Synthesis and characterization of compounds 3-8 have also been carried out successfully. The stability of biindenyl and its stereochemistry at position 2 and 2 was investigated using density functional theory.
Keywords
ab initio calculations , indene dimerization , bisindan , liquid crystals , Birch reduction
Journal title
letters in organic chemistry
Journal title
letters in organic chemistry
Record number
2717899
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