Title of article :
A Simple Preparation of Dihydrofullerene and Its Reversion to Fullerene (C60)
Author/Authors :
Wang, Guan-Wu Lanzhou University - State Key Laboratory of Applied Organic Chemistry, China , Wang, Guan-Wu University of Science and Technology of China - Department of Chemistry - Hefei National Laboratory for Physical Sciences at Microscale, China , Li, Yu-Jin Lanzhou University - State Key Laboratory of Applied Organic Chemistry, China , Li, Fa-Bao University of Science and Technology of China - Department of Chemistry - Hefei National Laboratory for Physical Sciences at Microscale, China , Liu, You-Cheng University ofScience and Technology of China - Department of Chemistry - Hefei National Laboratory for Physical Sciences at Microscale, China , Liu, You-Cheng Lanzhou University - State Key Laboratory of Applied Organic Chemistry, China
From page :
595
To page :
598
Abstract :
C60H2 was prepared in high yield by the reduction of C60 with either NaBH4 or Hantzsch esters.Dehydrogenation of hydrofullerenes to C60 by both organic and inorganic bases in the presence of air was achieved in 90-99% yield. Possible pathways for the conversion of C60H2 to C60 are proposed.
Keywords :
[60]Fullerene , dihydrofullerene , NaBH4 , Hantzsch ester
Journal title :
letters in organic chemistry
Journal title :
letters in organic chemistry
Record number :
2717910
Link To Document :
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