Title of article :
Use of Alkoxyallene Oxide and Titanium Tetraiodide/Titanium Tetraisopropoxide for the Conjugate Addition Reaction of Alkoxyacetone Enolate
Author/Authors :
Shimizu, Makoto Mie University - Department of Chemistry for Materials, Japan , Itohara, Susumu Mie University - Department of Chemistry for Materials, Japan
Abstract :
An enolate synthon of alkoxyacetone was regioselectively generated using alkoxyallene oxide and titanium tetraiodide/titanium tetraisopropoxide, and the subsequent conjugate addition reaction with enonesgave 4-alkoxy-1,5-diketones in good yields.
Keywords :
Alkoxyacetone , Alkoxyallene Oxide , Titanium Tetraiodide , Conjugate Addition
Journal title :
letters in organic chemistry
Journal title :
letters in organic chemistry
