Title of article :
Solvothermal In Situ Ligand Synthesis, Crystal Structure and Fluorescent Properties of a New Heterocyclic Compound 1, 1 - Bis{3-(Pyridin-2-yl)HImidazo[1, 5-alpha]Pyridine}
Author/Authors :
Liu, Cai-Ming Chinese Academy of Sciences - Center for Molecular Science, Institute of Chemistry - Beijing National Laboratory for Molecular Sciences, China , Gao, Hong-Yun Chinese Academy of Sciences - Center for Molecular Science, Institute of Chemistry - Beijing National Laboratory for Molecular Sciences, China , Zhang, De-Qing ChineseAcademy of Sciences - Center for Molecular Science, Institute of Chemistry - Beijing National Laboratory for Molecular Sciences, China , Zhu, Dao-Ben Chinese Academy of Sciences - Center for Molecular Science, Institute of Chemistry - Beijing National Laboratory for Molecular Sciences, China
Abstract :
Solvothermal in situ ligand reaction of bis(2-pyridinylmethyl)amine (bpa) in the presence of Fe(ClO4)2 × 6H2O and NaN3 yielded the crystalline fluorescent organic heterocyclic compound 1, 1 -bis{3-(pyridin-2-yl)H-imidazo[1, 5-a]pyridine} 1 and the by product Fe(bpa)2(ClO4)2 2. Compound 1 is the first example of imidazo[1, 5-a]pyridine compound synthesized by in situ reaction under solvothermal conditions.
Keywords :
Solvothermal synthesis, heterocyclic compound, imidazo[1, 5 , a]pyridine compound , iron(II) complex, crystalstructure, fluorescent property
Journal title :
letters in organic chemistry
Journal title :
letters in organic chemistry
