Title of article :
The Use of Enantiomerically Pure alpha,beta-Unsaturated N-Acyloxazolidin-2-Onein Diastereoselective Baylis-Hillman Type Reaction Mediated by SmI2
Author/Authors :
Mamaghani, Manouchehr University of Guilan - Faculty of Sciences - Department of Chemistry, رشت, ايران , Yazdanbakhsh, Mohammad Reza University of Guilan - Faculty of Sciences - Department of Chemistry, رشت, ايران , Badrian, Abed Research Institution for Curriculum Development Education Innovations, ايران , Valizadeh, Hassan azarbaijan shahid madani university - Faculty of Sciences - Department of Chemistry, تبريز, ايران , Samimia, Heshmat Allah University of Guilan - Faculty of Sciences - Department of Chemistry, رشت, ايران
Abstract :
(R)-3-(2-Bromo-3-phenyl-acryloyl)-5,5-dimethyl-4-phenyl-oxazolidin-2-one 3 which is readily available from (R)-phenylglycine, was shown to be an effective chiral auxiliary for stereoselective Baylis-Hillman type reaction with aldehydes in the presence of SmI2.
Keywords :
Baylis , Hillman , alpha , beta , unsaturated N , acyloxazolidin , 2 , one , samarium , diiodide , auxiliary , diastereoselective.
Journal title :
letters in organic chemistry
Journal title :
letters in organic chemistry
