Title of article :
Efficient and Selective Cleavage of Silyl Ethers with Antimony Trichloride
Author/Authors :
Wu, Qinpei Beijing Institute of Technology - Department of Biochemistry, China , Wang, Yuan Beijing Institute of Technology - Department of Biochemistry, China , Chen, Wei Beijing Institute of Technology - Department of Biochemistry, China , Wang, Hao Beijing Institute of Technology - Department of Biochemistry, China , Liu, Hua Beijing Institute of Technology - Department of Biochemistry, China
From page :
13
To page :
15
Abstract :
An efficient method for selective cleavage of silyl ethers mediated by SbCl3 in the presence of a number of function groups was described and the primary silyl ethers were hydrolized in the presence of the secondary ethers. The desilyl reaction took much longer time in dry solution than in wet.
Keywords :
Hydrolyses , catalysis , silyl ethers , antimony , protecting groups , desilylation
Journal title :
letters in organic chemistry
Journal title :
letters in organic chemistry
Record number :
2717956
Link To Document :
https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2717956
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