Author/Authors :
Takács, Eszter University of Veszprém - Department of Organic Chemistry - Hungary and Research Group for Petrochemistry of the Hungarian Academy of Sciences, Hungary , Skoda-Földes, Rita University of Veszprém - Department of Organic Chemistry - Hungary and Research Group for Petrochemistry of the Hungarian Academy of Sciences, Hungary , Ács, Péter University of Pécs - Department of Inorganic Chemistry, Hungary , Müller, Ernõ University of Pécs - Department of Inorganic Chemistry, Hungary , Kokotos, George University of Athens - Laboratory of Organic Chemistry, Greece , Kollár, László University of Pécs - Department of Inorganic Chemistry, Hungary , Kollár, László the Hungarian Academy of Sciences - Research Group for Chemical Sensors, Hungary
Abstract :
Methyl prolinate and benzyl prolinate were used as secondary amine nucleophiles in palladiumcatalysed aminocarbonylation of iodo-aromatics and iodo-alkenes. A mixture of 2-oxo-carboxamide and carboxamide type derivatives or pure carboxamides can be obtained by using iodo-benzene or iodo-alkenes assubstrates, respectively. The aminocarbonylation of iodo-alkenes in [bmim][PF6] ionic liquid was also carried out.
Keywords :
Aminocarbonylation , carbon monoxide , proline , palladium , ionic liquid
