Title of article :
Stereoselective Total Synthesis of (+)-Sedamine
Author/Authors :
Borah, Jagat C. Regional Research Laboratory - Natural Products Chemistry Division, India , Boruwa, Joshodeep Regional Research Laboratory - Natural Products Chemistry Division, India , Barua, Nabin C. Regional Research Laboratory - Natural Products Chemistry Division, India
Abstract :
A highly efficient stereoselective total synthesis of piperidine alkaloid (+)-sedamine has been described utilizing two regioselective ring opening reactions of epoxide with vinyl metallic reagent and a ringclosing metathesis reaction as the key steps.
Keywords :
(+) , sedamine , vinylmetallic reagent , ADH , regioselective epoxide opening , RCM
Journal title :
letters in organic chemistry
Journal title :
letters in organic chemistry
