Author/Authors :
Yang, Min Sichuan University - Department of Chemistry, China , Peng, Qian-Rong Guizhou Huang Guo Shu Tobacco Group Co - Technology Center, China , Song, Guang-Fu Guizhou University - Department of Chemistry Technology, China , Lan, Jing-Bo Sichuan University - Department of Chemistry, China , Wang, Dong-Shan Guizhou Huang Guo Shu Tobacco Group Co - Technology Center, China , You, Jing-Song Sichuan University - Department of Chemistry, China , Xie, Ru-Gang Sichuan University - Department of Chemistry, China
Abstract :
The catalytic system generated from ionic liquids, simple copper salts and terminal oxidant tertbutylhydroperoxide provided an efficient protocol for the allylic oxidation of ionone-like dienes to corresponding enones. Optimal conditions, short reaction time, and good yields were obtained. Coppernanop articles were found to be effective catalysts for the oxidation by TEM.
Keywords :
Allylic oxidation , ionone , like dienes , copper salt , nanoparticles , tert , butyl hydroperoxide , imidazolium ionicliquids
