Author/Authors :
Darabantu, Mircea Babes-Bolyai University - Department of Chemistry, Romania , Darabantu, Mircea Université de Rouen - I R C O F (Institut de Recherche en Chimie Organique Fine), France , Pintea, Monica Babes-Bolyai University - Department of Chemistry, Romania , Fazekas, Marijana Babes-Bolyai University - Department of Chemistry, Romania , Lameiras, Pedro Université de Rouen - I R C O F (Institut de Recherche en Chimie Organique Fine), France , Berghian, Camelia Babes-Bolyai University - Department of Chemistry, Romania , Delhom, Isabelle Université de Rouen - I R C O F (Institut de Recherche en Chimie Organique Fine), France , Silaghi-Dumitrescu, Ioan Babes-Bolyai University - Department of Chemistry, Romania , Plé, Nelly Université de Rouen - I R C O F (Institut de Recherche en Chimie Organique Fine), France , Turck, Alain Université de Rouen - I R C O F (Institut de Recherche en Chimie Organique Fine), France
Abstract :
The first convergent and non-protective synthesis of a G-2 melamine dendrimer having (1S,2S)-1,3-dihydroxy-1-(4-nitrophenyl)-prop-2-ylamino units as peripheral groups (from l-p-nitrophenylserinol) and piperazine as linker is described to occur in five linear steps and 27 % overall yield. The restricted rotation about Csp2(s-triazine)-N(exocyclic) bonds, exhibited by all compounds, is discussed as relevant.
Keywords :
Dendrimers , convergent approach , melamine , NMR , s , triazine
