Title of article :
Dielectric Properties of Ultra-Low Dielectric Constant PVA-Pentaerythritol/MnO2 Nanocomposite
Author/Authors :
Merza, S.H Depratment of Chemistry - College of Education for Pure Science (Ibn Al-Haitham) - University of Baghdad, Baghdad, Iraq , Fadil Mousa, E Department of Chemistry - College of Science for Women - University of Baghdad, Baghdad, Iraq
Abstract :
In this work, a simple method was used to prepare the MnO2 nanoparticles. These nanoparticles then were characterized by several techniques, such as X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy (SEM) and atomic force
microscope (AFM). The results showed that the diffraction peak of MnO2 nanoparticles was similar to that of standard data. The images of AFM and SEM indicated that the MnO2 nanorods were growing from the MnO2 nano spherical shape. PVA-pentaerythritol/MnO2
nanocomposite films were fabricated by evaporating casting method. The dielectric constant and loss tangent of P-Ery/MnO2 films were
measured between 10 kHz and 1 MHz using LCR. As the content of MnO2 increased, the dielectric constant decreased from 1.6 to 1.3. The
loss tangent of P-Ery was very low at 400 kHz, which increased by an increase in the MnO2 content. Thermogravimetric analysis and
Scanning electron microscope methods were used to investigate the thermal stability and surface analysis of the films.
Keywords :
Loss tangent , Clausius-Mossotti equation , MnO2 nanorod , Scanning electron microscopy (SEM) , X-ray diffraction (XRD)
Journal title :
Physical Chemistry Research