Title of article :
The D2d Structure and Easy Rotation around the C=C Bond of the TCNE Dianion
Author/Authors :
Uno، Bunji نويسنده , , Okumura، Noriko نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 1999
Abstract :
The structural and spectral characteristics of the tetracyanoethylene dianion (TCNE2-) have been investigated. The two-electron addition to the untibonding LUMO of TCNE causes the easy rotation around the C=C bond characterized by the formal single bond. The spectral measurements and MO calculations gives results that TCNE2- preferentially adopts the D2d and D2h structures in CH3CN and CH2Cl2, respectively
Keywords :
Goodness of fit , Model diagnosis , Identifiability , Parametric bootstrap , Restricted latent class models
Journal title :
CHEMISTRY LETTERS
Journal title :
CHEMISTRY LETTERS
