Title of article :
A Unique Chelating Effect of Sc(OTf)3 to Organofluorine Compounds
Author/Authors :
Hiyama، Tamejiro نويسنده , , Kajiro، Hiroshi نويسنده , , Mori، Atsunori نويسنده , , Nishihara، Yasushi نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 1999
Abstract :
The scandium trifluoromethanesulfonate-catalyzed cleavage of acetate bearing two or three fluorine atoms at a position (beta) to an acetoxy group proceeds exceptionally rapidly. The high efficiency of the hydrolysis is caused by a chelating effect of scandium with the fluorine atoms and an acetate moiety.
Keywords :
Bibliometrics , productivity rankings , refereed journals , research in probability and statistics
Journal title :
CHEMISTRY LETTERS
Journal title :
CHEMISTRY LETTERS