Title of article
Silapericyclyne, (Ph2SiC=C)6: Spontaneous Conformational Resolution of Boat- and Chair-‘Exploded’ Cyclohexane
Author/Authors
Unno، Masafumi نويسنده , , Matsumoto، Hideyuki نويسنده , , Saito، Takashi نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1999
Pages
-1234
From page
1235
To page
0
Abstract
The silapericyclyne, (Ph2SiC=C)6 was found to undergo spontaneous conformational resolution into the chair and boat conformations by crystallization from THF-MeOH. In solution, these two isomers rapidly interconvert, and could not be separately detected even at low temperature by 1H NMR.
Keywords
Goodness of fit , Identifiability , Model diagnosis , Parametric bootstrap , Restricted latent class models
Journal title
CHEMISTRY LETTERS
Serial Year
1999
Journal title
CHEMISTRY LETTERS
Record number
28076
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