• Title of article

    Silapericyclyne, (Ph2SiC=C)6: Spontaneous Conformational Resolution of Boat- and Chair-‘Exploded’ Cyclohexane

  • Author/Authors

    Unno، Masafumi نويسنده , , Matsumoto، Hideyuki نويسنده , , Saito، Takashi نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 1999
  • Pages
    -1234
  • From page
    1235
  • To page
    0
  • Abstract
    The silapericyclyne, (Ph2SiC=C)6 was found to undergo spontaneous conformational resolution into the chair and boat conformations by crystallization from THF-MeOH. In solution, these two isomers rapidly interconvert, and could not be separately detected even at low temperature by 1H NMR.
  • Keywords
    Goodness of fit , Identifiability , Model diagnosis , Parametric bootstrap , Restricted latent class models
  • Journal title
    CHEMISTRY LETTERS
  • Serial Year
    1999
  • Journal title
    CHEMISTRY LETTERS
  • Record number

    28076