Title of article :
Silapericyclyne, (Ph2SiC=C)6: Spontaneous Conformational Resolution of Boat- and Chair-‘Exploded’ Cyclohexane
Author/Authors :
Unno، Masafumi نويسنده , , Matsumoto، Hideyuki نويسنده , , Saito، Takashi نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 1999
Abstract :
The silapericyclyne, (Ph2SiC=C)6 was found to undergo spontaneous conformational resolution into the chair and boat conformations by crystallization from THF-MeOH. In solution, these two isomers rapidly interconvert, and could not be separately detected even at low temperature by 1H NMR.
Keywords :
Goodness of fit , Identifiability , Model diagnosis , Parametric bootstrap , Restricted latent class models
Journal title :
CHEMISTRY LETTERS
Journal title :
CHEMISTRY LETTERS
