Title of article
Synthesis and Structure of Chiral (R)-2,2-Bis-Silyl-Substituted 1,1-Binaphthyl Derivatives
Author/Authors
Suzuki، Toshio نويسنده , , Hoshi، Takashi نويسنده , , Shionoiri، Hiroshi نويسنده , , Ando، Masayoshi نويسنده , , Hagiwara، Hisahiro نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1999
Pages
-1244
From page
1245
To page
0
Abstract
First synthesis of optically active 2,2ʹ-bis-silyl-substituted 1,1ʹ-binaphthyl derivatives, (R)-(+)-2,2ʹ-bis(trimethylsilyl)-1,1ʹbinaphthyl ((R)-(+)-1) and (R)-(-)-2,2ʹ-bis(dimethylphenylsilyl)-1,1ʹ-binaphthyl ((R)-(-)-2), has been accomplished by the direct bis-silylation of chiral 2,2ʹ-dibromo-1,1ʹ-binaphthyl (DBBN). The molecular structure and the absolute configuration of (R)-(-)-2 have been determined by means of X-ray crystallography
Keywords
Identifiability , Model diagnosis , Restricted latent class models , Parametric bootstrap , Goodness of fit
Journal title
CHEMISTRY LETTERS
Serial Year
1999
Journal title
CHEMISTRY LETTERS
Record number
28096
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