Synthesis of Linear Fullerene-Containing Polysiloxanes and Their Application to Capillary Gas Chromatography

Fullerene-containing polysiloxanes were prepared by reacting [60]fullerene with azidoalkyl polysiloxanes directly, and characterized by FT-IR, UV-Vis, ʹH-NMR and C-NMR. The polymers were used as stationary phases in capillary gas chromatography. Many organic compounds, especially high boiling substance or aromatic or alcohol positional isomers, were separated effectively on these columns.