Title of article
Dimerization of Ethynylcyclopentadienylmetal Complexes
Author/Authors
Yamazaki، Hiroshi نويسنده , , Suzuki، Yasunobu نويسنده , , Hirotani، Ryuichi نويسنده , , Komatsu، Hiroaki نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1999
Pages
-1298
From page
1299
To page
0
Abstract
Heating of bulky ethynyltetramethylcyclopentadienylmetal complexes, RCCH (R = Me4C5Rh(cod), Me4C5Ir(cod), Me4C5Fe (C5Me4H)), in the presence of catalytic amounts of Ru(H)2(CO)(PPh3)3 afforded the corresponding butatriene, RCH=C=C=CHR. The rhodium complex was stepwise hydrogenated by Ru(H)2(CO)(PPh3)3 to give a butadiene complex, RCH=CH–CH=CHR, whose molecular structure was determined by X-ray diffraction analysis.
Keywords
Goodness of fit , Identifiability , Parametric bootstrap , Restricted latent class models , Model diagnosis
Journal title
CHEMISTRY LETTERS
Serial Year
1999
Journal title
CHEMISTRY LETTERS
Record number
28204
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