Title of article
Self-assembly of Tetramethylated Resorcin[4]arene to Form Molecular Capsules Incorporating Methanol, Ethanol, and Imidazole: A Comparison with the Unsubstituted Resorcin[4]arene System
Author/Authors
Aoki، Katsuyuki نويسنده , , Nagae، Toshiki نويسنده , , Matsubara، Rei نويسنده , , Fujisawa، Ikuhide نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
-1263
From page
1264
To page
0
Abstract
Tetramethylated resorcin[4]arene (MRCT) forms ʹhead-to-headʹ arranged self-dimers incorporating neutral guest molecules methanol, ethanol, and imidazole within the cavity, with the MRCT:guest composition of 2:2, while unsubstituted resorcin[4] arene forms 1:1 monomers, showing the significance of the methyl substituents of the MRCT rings in the capsule formation through methyl···methyl hydrophobic interactions between the facing substructures, as evidenced by X-ray diffraction.
Keywords
Application-production research , Genetic-fuzzy system , prediction , Power requirement , Surface finish , grinding
Journal title
CHEMISTRY LETTERS
Serial Year
2004
Journal title
CHEMISTRY LETTERS
Record number
28790
Link To Document