Molecular weight distribution of Pinus radiata kraft mill wastewater treated by anaerobic digestion

Kraft mill is responsible for massive discharge of highly polluted e‚uents. The main characteristics of this e‚uent are high toxicity and low biodegradability due to tannin, lignin and chlorophenol compounds. The composition may vary dramatically depending, for instance, on the utilised feedstock and process. The purpose of this work was to investigate the molecular weight distribution of Pinus radiata kraft pulping wastewater treated by anaerobic digestion by using two types of anaerobic reactors: ®xed bed and sludge blanket. Anaerobic sludge blanket (UASB) and anaerobic ®lter (AF) were operated. In both reactors, the total alkalinity ranged between 1.0 and 1.5 g CaCO3=l, while the organic load rate (OLR) was increasing during operation from 1.2 to 3:3 gCOD=l d. COD and total phenolic compounds …UV215† removal ranged between 30±50% and 13±20%, respectively, while the BOD5 removal ranged 60± 90%. However only a partial biodegradation (10±43%) of tannin and lignin was observed. Results from ultra®ltration analyses indicated that the fraction with a molecular weight (MW) <1000, COD and colour decreased after anaerobic treatment, but the total phenolic compounds increased. In the 1000 < MW < 10; 000 fraction, there was no change in COD, UV215 and colour. In the >10,000 MW fraction, colour and COD fraction increased by 14% and 5%, respectively, after anaerobic treatment. It can be concluded from this study, that treatment with UASB or AF reactors is not enough, under the conditions tested, for a large COD removal from Pinus radiata wastewater