Buoyancy corrections for the potential of an impurity in a 4He nanodroplet

This paper presents correction terms for the effective potential for the translation and rotation of an impurity atom or molecule solvated in a helium nanodroplet that were previously published (LEHMANN, K. K.,1999, Molec. Phys., 97, 645). The correction arises from changes in the total He-He potential energy of the displaced liquid as a function of the solute position within the droplet. For the alkali atoms, this buoyancy type correction removes the large barrier to ejection of the atom from the droplets, which is predicted if this term is neglected.