Viscosity of Binary Mixtures of Alkyl Acetates with Hexane, Tetrachloromethane, and Trichloromethane

The viscosity n for binary mixtures of methyl acetate (MA), ethyl acetate (EA), n-amyl acetate (nAA), isoamyl acetate (iAA), decyl acetate (DeA), and dodecyl acetate (DoA) with hexane and of MA, EA, nAA, and iAA with tetrachloromethane and trichloromethane has been measured at 303.15 K. over the entire range of composition. The viscosity data have been correlated with the equations of Grunberg and Nissan; Hind, McLaughlin, and Ubbelohde; Tamura and Kurata; Katti and Chaudhri; McAllister; Heric and Brewer; and Auslaender. The viscosity deviations Dn and excess Gibbs energy of activation DG*E of viscous flow based on Eyringʹs theory have been calculated. The results have been analyzed in terms of disruption of dipolar association of alkyl acetate and molecular iInteraction between alkyl acetate and chloromethane.