Title of article :
Densities, Sound Speeds, Excess Volumes, and Excess Isentropic Compressibilities of Methyl Acrylate + 1-Propanol (or 1-Butanol) + Hydrocarbons(n-Hexane, n-Heptane, Cyclohexane, Benzene, and Toluene) at 308.15 K
Author/Authors :
P. Bahadur and N. V. Sastry ، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Pages :
16
From page :
447
To page :
462
Abstract :
Densities and sound speeds of ten ternary mixtures of methyl acrylate (1)+ 1-propanol (2) or 1-butanol (2)+n-hexane (3), +n-heptane (3), +cyclohexane (3), +benzene (3), and +toluene (3) have been measured at 308.15 K. The excess volumes, VE, and excess isentropic compressibilities, oEs , have been estimated. These two experimentally derived excess functions were also compared with those predicted by empirical equations of Redlich–Kister, Kohler, and Tsao–Smith. A qualitative analysis of VE and oEs data of ternary mixtures reveals that in MA (1)+1-alcohols (2)+n-hexane (3), +n-heptane (3), and +cyclohexane (3), structure disruptions are more predominant while in MA (1)+1-alcohols (2)+benzene (3) or +toluene (3) mixtures, the weak but specific structure making iInteractions dominate. A perusal of deviations between the experimental and calculated VE and oEs results shows that the predictive expressions give only a rough estimate of the functions for the ten studied mixtures.
Keywords :
n-Heptane , sound speeds , ternary mixtures , methyl acrylate , Benzene , n-Hexane , Cyclohexane , excess volumes , excess isentropic compressibilities , 1-propanol , toluene. , Densities , 1-butanol
Journal title :
International Journal of Thermophysics
Serial Year :
2003
Journal title :
International Journal of Thermophysics
Record number :
426952
Link To Document :
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