Title of article :
Thermophysical Properties of Nonelectrolyte Mixtures. Densities, Viscosities, and Sound Speeds of Binary Mixtures of Methyl Methacrylate+Branched Alcohols (Propan-2-ol, 2-Methylpropan-1-ol, Butan-2-ol, and 2-Methylpropan-2-ol) at T=298.15 and 308.15 K
Author/Authors :
N. V. Sastry and J. George ، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
Measurements of the densities, viscosities, and sound speeds at T=298.15 and
308.15 K for the binary mixtures of methyl methacrylate+propan-2-ol, +2-
methylpropan-1-ol, +butan-2-ol, and +2-methylpropan-2-ol are made over the
complete composition range. From the measured data, excess isentropic
compressibilities have been calculated. The mixture viscosities have been
correlated by the Grunberg–Nissan, McAllister, and Auslander equations, while
the sound speed in binary mixtures has been analyzed using free length and
collision factor theories, and Junjie and Nomoto equations. The excess isentropic
compressibilities, oEs
are fitted to a third degree polynomial equation. The
qualitative analysis of oEs
have been made in terms of bulk molecular iInteractions.
The conclusions drawn were supplemeInted by examining the variation of
relative association and solvation numbers over the complete composition
range.
Keywords :
Binary mixtures , Densities , 2-methylpropan-2-ol , 2-methylpropan-1-ol , sound speeds , propan-2-ol , viscosities , Methyl methacrylate , butan-2-ol , excess isentropiccompressibilities
Journal title :
International Journal of Thermophysics
Journal title :
International Journal of Thermophysics