Title of article
Solvation of lithium ions in organic electrolytes of primary lithium batteries by electrospray ionization-mass spectroscopy
Author/Authors
Tsuyoshi Fukushima، نويسنده , , Yoshiharu Matsuda، نويسنده , , Hiroyuki Hashimoto، نويسنده , , Ryuichi Arakawa، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
4
From page
34
To page
37
Abstract
Solvation of lithium ions in the organic electrolyte solutions for primary lithium batteries was investigated by electrospray ionization-mass spectroscopy (ESI-MS). In LiBF4/γ-butyrolactone (GBL), lithium ions were solvated to GBL molecules in the form [Li(GBL)2]+ or [Li(GBL)3]+, and in LiClO4/ dimethoxyethane (DME)–propylene carbonate (PC), lithium ions were solvated mainly to DME and PC in the form [Li(DME)(PC)]+.
Keywords
Electrospray ionization-mass spectroscopy , Solvation of lithium ion , Organic electrolyte solutions , Dimethoxyethane , Propylene carbonate
Journal title
Journal of Power Sources
Serial Year
2002
Journal title
Journal of Power Sources
Record number
443912
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