Durability of resin bonds to a cobalt-chromium alloy

Common nickel-chromium-beryllium alloys used for resin-bonded fixed partial dentures have possible health hazards due to leaching of nickel and beryllium. For resin-bonded restorations corrosion resistant cobalt-chromium alloys (CoCr) are a suitable alternative material without sacrificing physical properties. This study evaluated the bond strength and bond durability of new adhesive systems to a CoCr alloy. Plexiglas (acrylic) tubes filled with composite were bonded to CoCr alloy discs. Groups of 24 samples were bonded using six different bonding systems. Subgroups of eight bonded samples were stored in an isotonic artificial saliva solution (37 °C) either for 1 day, 30 days or 150 days. In addition the 30- and 150-days samples were subjected to 7500 or 37 500 thermal cycles, respectively. The bond strength of a conventional BisGMA composite (Twinlook) to sandblasted CoCr was significant lower than when using chemomechanical bonding systems and decreased continuously during the storage time of 150 days. The additional use of silane on the sandblasted alloy resulted in an insignificant increase in bond strength. Statistically significant higher and more durable bonds to CoCr alloy were achieved either with the combination of silica coating and use of the conventional BisGMA composite or with the combination of sandblasting and the use of a composite modified with a phosphate monomer (Panavia EX). In the latter systems, the bond strengths were mainly limited by the cohesive strength of the resin composites; partial adhesive failures were only observed for a tribochemical silica coating system. A new composite also containing the active phosphate monomer (Panavia TPN-S) exhibited a significant decrease in cohesive strength over time.