Thermodynamic assessment of the Al---Ru system

The CALPHAD technique was used to calculate the Al---Ru binary phase diagram. The RuAl (B2) phase was described with the sublattice model (SL), also designated Compound Energy Formalism (CEF), as well as the Modified Sublattice Formalism (MSL), which describes the order disorder transformation with one Gibbs energy function. The RuAl6 phase was described as a stoichiometric phase and the remaining intermetallic phases (Ru4Al13, RuAl2 and Ru2Al3) were modelled with the sublattice model. The solubility of Ru in (Al) was considered negligible. Good agreement was obtained between the calculated and the experimental phase diagrams.