Phase diagrams for liquid–liquid and liquid–solid equilibrium of the ternary poly ethylene glycol di-methyl ether 2000 + tri-sodium phosphate + water system at different temperatures and ambient pressure

Complete phase diagrams for the poly ethylene glycol di-methyl ether 2000 (PEGDME2000)+Na3PO4+H2O system at T = (298.15, 308.15 and 318.15) K were determined. Liquid–liquid equilibria (LLE) for the aqueous PEGDME2000+Na3PO4 system were determined experimentally at T = (298.15, 308.15, 313.15 and 318.15) K. The effects of temperature on the binodals and tie-lines of the investigated aqueous two-phase system (ATPS) were also studied. Furthermore, the modified local composition segment-based NRTL and Wilson models and also osmotic virial equation were used for the correlation and prediction of the liquid–liquid phase behavior of the studied system.