Assay of 222Rn in water samples by a modified integral counting method

222Rn activity concentrations in water collected from 163 private wells and 14 springs in Tokyo were measured with a liquid scintillation spectrometer using a modified integral counting method. The activity concentrations of 222Rn range from 0.2 to 22.9 Bq/L and average 4.8 Bq/L. The errors due to the air luminescence counts and the interferences from 220Rn and 219Rn are discussed and evaluated. 222Rn samples of 0.2 Bq/L can be assayed within an overall uncertainty of 3.1%. The liquid scintillation method involving agitation of the sample water directly with a liquid scintillation cocktail was compared with the present method and evaluated.