The Phase Relations in the System In2O3-TiO2-MgO at 1100 and 1350°C

The crystal structure of La(H2O)2K(C2O4)2·H2O has been solved ab initio from powder diffraction data collected with conventional monochromatic X-rays. The symmetry is monoclinic, space group C2/m, cell dimensions a=22.033(1) ?, b=7.6003(5) ?, c=6.6418 (4) ?, beta=103.814(6)°, V=1080.05(8) ?3, Z=4. Since a disorder of one oxalate group is observed with all possible monoclinic space groups, it has been found convenient to describe the crystal structure in a triclinic subcell. The disorder problem is thoroughly discussed with respect to the powder diffraction data available for this material. From this description the compound exhibits a layered-type structure, which could explain reported cation-exchange properties. The layers are formed by four-membered rings [La(C2O4)]4. The potassium atom and two of the three water molecules are located between the layers. The third water molecule lies on the layer in tunnels with a diamond-shaped cross section. The lanthanum atom is tenfold-coordinated in a distorted bicapped square antiprism and the potassium atom is eightfold-coordinated in a dodecahedron. The crystal structure of La(H2O)2(NH4)(C2O4)2· H2O is isostructural with that of La(H2O)2K(C2O4)2·H2O [a=22.130(4) ?, b=7.774(1) ?, c=6.655(2) ?, beta=105.28(2)°, V=1104.4(3) ?3]. The thermal decomposition of these two precursors has been carried out by means of temperature-dependent X-ray diffraction and TG-DSC. The dehydration leads to anhydrous phases, which are amorphous and poorly crystalline for the potassium and ammonium compounds, respectively. Amorphous LaK (C2O4)2 crystallizes at 260°C. Its symmetry is monoclinic with the cell dimensions a=5.687 (3) ?, b=15.241(5) ?, c=9.017(4) ?, beta=92.82(3)°. At higher temperature, the decomposition of LaK(C2O4)2 yields La2O2CO3 (Type-Ia), La2O2CO3 (Type-II), and pure La2O3, successively. La(NH4)(C2O4)2 leads to La2O2CO3 (Type-II) and, finally, La2O3