• Title of article

    Synthesis and Characterization of Reduced Molybdenum Oxides with Hydroxylamine Hydrochloride in Aqueous Solutions

  • Author/Authors

    Goodenough، J. B. نويسنده , , Manivannan، V. نويسنده , , Tichy، R. نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 1999
  • Pages
    -268
  • From page
    269
  • To page
    0
  • Abstract
    Reduction of ammonium molybdate, (NH4)6Mo7O24·4H2O, with hydroxylamine hydrochloride. NH2OH·HCl, at ambient temperature in aqueous solutions results in amorphous MoO3·nH2O oxide. Subsequent heat treatment of this oxide yields Mo1delta O2 or a hydrogen molybdenum bronze, HxMoO3 (x~1), both crystalline in nature. The samples have been characterized by X-ray diffraction, differential scanning calorimetry, scanning and transmission electron microscopies, thermogravimetric analysis, infrared spectroscopy, and galvanostatic electrochemical characterization.
  • Keywords
    group 15 elements , Peierls distortion , structural distortions , Fermi surface nesting , band structure calculations , s–p mixing
  • Journal title
    JOURNAL OF SOLID STATE CHEMISTRY
  • Serial Year
    1999
  • Journal title
    JOURNAL OF SOLID STATE CHEMISTRY
  • Record number

    56933

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=56933