The Upper Limit of the Solid Solution Bi2-x SbxMoO6: Structure Refinement of Bi1.1Sb0.9MoO6

The space groups of three previously described Mo(V) phosphate structures are revised. (1) DELTA-KMo2P3O13, originally reported as triclinic, P , is revised to monoclinic, C2/c; it is identical to the compound previously identified as K4Mo8P12O52. (2) The compound formulated as [Mo12CdP8O50(OH)12]Cd [N(CH3)4]2(H3O)6·5H2O, originally described as monoclinic, Pn, is revised to P21/n (also monoclinic). (3) Rb3O2(MoO)4(PO4)4, originally reported as orthorhombic, C2221, is revised to tetragonal, P43212. The general descriptions of the structures are unchanged; however, for compound 2 the revision involves the addition of a center of symmetry and, as a result, there are significant changes in the interatomic distances and angles.