Bioavailability of Metals in Sediments of the Dogger Bank (Central North Sea): A Mesocosm Study

Analyses of radionuclide activity, particle size distribution, elemental composition and magnetic properties of saltmarsh and mudflat sediments from the eastern Irish Sea were undertaken in order to identify potential grain-size proxies which could aid long-term modelling of radionuclide activity in this area.241Am and137Cs concentrations were found to be highly dependent upon the presence of sediment finer than 5phi, highlighting the need to utilize this fraction in preference to conventional normalization procedures which refer to the abundance of sediment finer than 4phi. Analyses of potential grain-size proxies for radionuclide activity highlighted a similar grain-size association with respect to sediment magnetic properties. This was linked to the influence of organic carbon on microbial populations responsible for mineral magnetism. Regression analysis was employed to derive a method whereby radionuclide concentration can be predicted using magnetic data as a grain-size proxy, thereby facilitating the identification of spatial and temporal trends in activity data.