Concerning the transformations of Ti3Ir alloy during high-energy ball-milling

Thermodynamically stable Ti3Ir with the Cr3Si (A15)-type crystal structure can gradually be transformed into a metastable Ti3Ir alloy with a bcc crystal structure by high-energy ball-milling for 12.5 h. The long-term ball-milling for up to 112 h, however, is accompanied by a solid-state reaction between Ti3Ir and the vial material leading to the formation of a nano-crystalline or amorphous MgZn2-type phase with the Ti(Fe1.85Ir0.15) stoichiometry and a micro-crystalline thermodynamically stable CsCltype phase. Both the CsCl- and MgZn2-type phases were obtained in the crystalline form after annealing ball-milled Ti3Ir. Properties of the A15 Ti3Ir alloy changed considerably after ball-milling. The superconducting transition observed in the original A15 alloy at ~4.3 K no longer exists in the ball-milled material. The electrochemically determined hydrogen storage capacity of the ball-milled alloy also decreases in comparison to the A15 material from 269 to 104 mAh/g. On the contrary, the electrochemical discharge capacity of Ti3Ir increases from 45 to 104 mAh/g after ball-milling.