Author/Authors :
Tolis، Evangelos J. نويسنده , , Manos، Manolis J. نويسنده , , Terzis، Aris نويسنده , , Raptopoulou، Catherine P. نويسنده , , Kabanos، Themistoklis A. نويسنده ,
Abstract :
Sequential addition of bipy, or phen followed by H3mpg (a sulfhydryl-containing pseudopeptide) and AcONa·2H2O to VIVOSO4·5H2O in the presence of oxygen yields [(VIVO)2(mu-OH)(mu-OAc)(mu-H2mpgS-S)2L2]·xMeOH·yH2O (L = bipy, 1·1.68MeOH·0.75H2O or phen, 2·1.40MeOH· 0.81H2O), containing the oxidized-S,S dimer of H3mpg [H2mpgS-S2-]; [(VIVO)2(mu-OH)(mu-OAc)(OAc)2(bipy)2]3 was also prepared in a similar way to 1·1.68MeOH·0.75H2O using reduced glutathione instead of H3mpg.
