Author/Authors :
Wang، Enbo نويسنده , , Huang، Rudan نويسنده , , Hu، Changwen نويسنده , , Jia، Hengqing نويسنده , , Hu، Ninghai نويسنده , , Li، Yangguang نويسنده , , De، Gejihu نويسنده , , Yuan، Mei نويسنده ,
Abstract :
A novel organic–inorganic hybrid compound [Cu(phen)]2[VIVV4VAs2VO19]·0.5H2O 1 has been hydrothermally synthesized. Its structure, determined by single crystal X-ray diffraction, exhibits an unusual two-dimensional Aarsenic vanadate layered network grafted with the [Cu(phen)]2+ complex. The chelating phen ligands project perpendicularly beyond the inorganic layer. Variable temperature magnetic susceptibility studies indicate that both ferro- and antiferro-magnetic interactions exist in 1.