Title of article :
An Accurately-Constructed Structural Model for an Active Site of Fe-Containing Superoxide Dismutases (Fe-SODs)
Author/Authors :
Masuda، Hideki نويسنده , , Funahashi، Yasuhiro نويسنده , , Jitsukawa، Koichiro نويسنده , , Yamaguchi، Syuhei نويسنده , , Kumagai، Akinori نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
A novel structural model, [Fe(bpga)(N3)(OCH3)] (1) (BPGA: bis(6-pivalamido-2-pyridylmethyl)(carboxy-methyl)amine), for an active site of Fe-containing SOD enzyme with N3 has been accurately designed and prepared, which has been characterized by X-ray structure analysis and UV-vis, ESR, and IR spectroscopies. Reaction of 1 with acid/base in methanol has shown that the superoxide-accessible site is the N3-coordination site in the equatorial plane.
Keywords :
meristem culture , peppermint , certification , Mentha , spearmint , Verticillium wilt
Journal title :
INORGANIC CHEMISTRY
Journal title :
INORGANIC CHEMISTRY
