Title of article
The Cation-Deficient Ruddlesden-Popper Oxysulfide Y2Ti2O5S2 as a Layered Sulfide: Topotactic Potassium Intercalation To Form KY2Ti2O5S2
Author/Authors
Rutt، Oliver J. نويسنده , , Hill، Timothy L. نويسنده , , G?l، Zolt?n A. نويسنده , , Hayward، Michael A. نويسنده , , Clarke، Simon J. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-7905
From page
7906
To page
0
Abstract
Potassium intercalation into the cation-deficient n = 2 Ruddlesden-Popper oxysulfide Y2Ti2O5S2 to form KY2Ti2O5S2 has been carried out by reaction of the oxysulfide with potassium vapor in sealed metal tubes at 400 °C, potassium naphthalide in THF at 50 °C, or potassium in liquid ammonia at temperatures as low as -78 °C. Insertion of potassium is topotactic, and although a site 12-coordinate by oxide ions is vacant in the perovskite-...
Keywords
spearmint , Verticillium wilt , certification , meristem culture , Mentha , peppermint
Journal title
INORGANIC CHEMISTRY
Serial Year
2003
Journal title
INORGANIC CHEMISTRY
Record number
66436
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