A Solvothermally in Situ Generated Mixed-ligand Approach for NLO-Active Metal-Organic Framework Materials

The synthesis and crystal structures of two new NLO-active coordination polymers, [Zn(2-pc)(4-pc)] and [Cd(2-pc)(4-pc)(H2O)]·N2H4 (2-pc = 2-pyridine carboxylate, 4-pc = 4-pyridine carboxylate), bridged by in situ generated mixed ligands under solvothermal treatment is described.