Title of article
Thermodynamic Investigation of the Molecular Interactions of 4-Nitrophenol with Free-Bases meso-Tetraarylporphyrins
Author/Authors
A. Zabardasti and Z. Rezvani-Abkenari، نويسنده ,
Issue Information
فصلنامه با شماره پیاپی سال 2008
Pages
5
From page
57
To page
61
Abstract
The molecular interactions of 4-Nitrophenol (4NP) with free-base meso-tetraarylporphyrins (H2T(4-X)PP; X = OCH3, CH3, H,Cl) have been studied. The formation constants and other thermodynamic parameters were calculated by using UV-Vis spectrophotometry titration results. The formation constants show the following trend relative to X substituent of porphyrins: H2T(4-CH3O)PP > H2T(4-CH3)PP > H2TPP > H2T(4-Cl)PP
Keywords
4-Nitrophenol , Free-base porphyrins , H-bond complexes , Molecular interaction , Noncovalent bonding
Journal title
Journal of the Iranian Chemical Society (JICS)
Serial Year
2008
Journal title
Journal of the Iranian Chemical Society (JICS)
Record number
666593
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