Synthesis, Structure and Magnetic Property of [Ce(DMSO)2(H2O)Fe(CN)6]

The title complex, [Ce(DMSO)2(H2O)Fe(CN)6] (1), was obtained by solution reactions and structurally characterized by X-ray diffraction. The title complex is characteristic of a novel cyano-bridged two-dimensional stair-like layered structure. The magnetic property of the title complex is reported herein. The χMT value at 300 K is ca. 0.92 emu K mol-1. The temperature dependence behavior of molar magnetic susceptibility of the complex clearly indicates the presence of an antiferromagnetic interaction.