Title of article
Studies on the Synthesis and Dynamic NMR Properties of 2-(Benzylidene amino)-N-[(R)-2-hydroxy-2-methyl-1-phenylpropyl]acetami
Author/Authors
H.A. Samimi، نويسنده , , M. Mamaghani، نويسنده , , K. Tabatabeian and H.R. Bijanz، نويسنده ,
Issue Information
ماهنامه با شماره پیاپی سال 2010
Pages
5
From page
185
To page
189
Abstract
An efficient method was employed for the preparation of 2-(benzylideneamino)-N-[(R)-2-hydroxy-2-methyl-1-phenylpropyl] acetamide utilizing optically pure (R)-5,5-dimethyl-4-phenyloxazolidin-2-one. This product showed interesting dynamic NMR properties for the methylene protons adjacent to the azomethine group (ΔG‡ = 15.1 ± 0.1 kcal mol-1).
Keywords
Chiral azomethine , azomethine ylide , chiral auxiliary , dynamic NMR
Journal title
Journal of the Iranian Chemical Society (JICS)
Serial Year
2010
Journal title
Journal of the Iranian Chemical Society (JICS)
Record number
666918
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