Title of article :
The First Structurally Confirmed Paddlewheel Compound with an M2^(7+) Core: [Os2(hpp)4Cl2](PF6)
Author/Authors :
Cotton، F. Albert نويسنده , , Huang، Penglin نويسنده , , Murillo، Carlos A. نويسنده , , Wang، Xiaoping نويسنده , , Dalal، Naresh S. نويسنده , , Stowe، Ashley C. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The coordination chemistry of the oxadiazole-containing rigid bidentate ligands 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (L2) and 2,5-bis(4-aminophenyl)-1,3,4-oxadiazole (L3) with inorganic Ag(l) salts has been investigated. Four new coordination polymers were prepared by solution reactions and fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. {[Ag(L2)]SO3CF3}n (1) (triclinic, PI; a = 10.1231(7) A, b = 13.9340-...
Keywords :
Radicals Intermediates , Trihalides , Regiochemistry , Alicyclic Aliphatic Substrates , (alpha)Carbon , Cycloalkyl Halides , EWG , Neopentyl , Nitroalkanes , Aliphatic Substrates , Carbonylation , sp2 Carbons , Cumyl , sp3 Carbons , Heterocyclic Analogues , Carbanions , stereochemistry , Triorganylstannyl , Oxygen , Nitrogen Nucleophiles , Sulfur Nucleophiles , Phosphorus Nucleophiles , Nitrobenzyl , Photostimulated Reactions , Geminal Dihalides
Journal title :
INORGANIC CHEMISTRY
Journal title :
INORGANIC CHEMISTRY