Title of article :
Solution-State and Solid-State Structural Characterization of Complexes of a New Macrocyclic Ligand Containing the 1,5Diazacyclooctane Subunit
Author/Authors :
Hu، Chuanjiang نويسنده , , Wagenknecht، Paul S. نويسنده , , Nathan، Lawrence C. نويسنده , , Nguyen، Thoi D. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The coordination chemistry of the oxadiazole-containing rigid bidentate ligands 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (L2) and 2,5-bis(4-aminophenyl)-1,3,4-oxadiazole (L3) with inorganic Ag(l) salts has been investigated. Four new coordination polymers were prepared by solution reactions and fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. {[Ag(L2)]SO3CF3}n (1) (triclinic, PI; a = 10.1231(7) A, b = 13.9340-...
Keywords :
stereochemistry , Triorganylstannyl , Aliphatic Substrates , Carbonylation , (alpha)Carbon , Cycloalkyl Halides , Nitrogen Nucleophiles , Nitroalkanes , Carbanions , Radicals Intermediates , Trihalides , Photostimulated Reactions , Geminal Dihalides , Nitrobenzyl , sp3 Carbons , Heterocyclic Analogues , Regiochemistry , Alicyclic Aliphatic Substrates , Oxygen , Sulfur Nucleophiles , sp2 Carbons , Cumyl , Phosphorus Nucleophiles , EWG , Neopentyl
Journal title :
INORGANIC CHEMISTRY
Journal title :
INORGANIC CHEMISTRY