Title of article :
Synthesis, Crystal Structure, and Magnetic Properties of {[Cu(oxbe)]Mn(H2O)[Cu(oxbe)(DMF)]}n·nDMF·nH2O: From Dissymmetrical Mononuclear Entities to a 3D Heterometallic Supramolecular Coordination Polymer
Author/Authors :
Liao، Daizheng نويسنده , , Hu، Ninghai نويسنده , , Zang، Shuang-Quan نويسنده , , Tao، Ruo-Jie نويسنده , , Wang، Qing-Lun نويسنده , , Cheng، Yan-Xiang نويسنده , , Niu، Jing-Yang نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The coordination chemistry of the oxadiazole-containing rigid bidentate ligands 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (L2) and 2,5-bis(4-aminophenyl)-1,3,4-oxadiazole (L3) with inorganic Ag(l) salts has been investigated. Four new coordination polymers were prepared by solution reactions and fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. {[Ag(L2)]SO3CF3}n (1) (triclinic, PI; a = 10.1231(7) A, b = 13.9340-...
Keywords :
Regiochemistry , Alicyclic Aliphatic Substrates , Aliphatic Substrates , Carbonylation , stereochemistry , Triorganylstannyl , (alpha)Carbon , Cycloalkyl Halides , Oxygen , Sulfur Nucleophiles , Nitroalkanes , Phosphorus Nucleophiles , Nitrobenzyl , sp2 Carbons , Cumyl , sp3 Carbons , Heterocyclic Analogues , Photostimulated Reactions , Geminal Dihalides , Radicals Intermediates , Trihalides , EWG , Neopentyl , Carbanions , Nitrogen Nucleophiles
Journal title :
INORGANIC CHEMISTRY
Journal title :
INORGANIC CHEMISTRY
