Title of article :
Subtle Role of Polyatomic Anions in Molecular Construction: Structures and Properties of AgX Bearing 2,4-Thiobis(pyridine) (X- = NO3-, BF4-, ClO4-, PF6-, CF3CO2-, and CF3SO3-)
Author/Authors :
Lee، Young-A نويسنده , , Jung، Ok-Sang نويسنده , , Kim، Yun Ju نويسنده , , Park، Ki-Min نويسنده , , Lee، Shim Sung نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The coordination chemistry of the oxadiazole-containing rigid bidentate ligands 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (L2) and 2,5-bis(4-aminophenyl)-1,3,4-oxadiazole (L3) with inorganic Ag(l) salts has been investigated. Four new coordination polymers were prepared by solution reactions and fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. {[Ag(L2)]SO3CF3}n (1) (triclinic, PI; a = 10.1231(7) A, b = 13.9340-...
Keywords :
Sulfur Nucleophiles , Nitrobenzyl , sp2 Carbons , Cumyl , Radicals Intermediates , Trihalides , Regiochemistry , Alicyclic Aliphatic Substrates , stereochemistry , Triorganylstannyl , Photostimulated Reactions , Geminal Dihalides , sp3 Carbons , Heterocyclic Analogues , Aliphatic Substrates , Carbonylation , EWG , Neopentyl , (alpha)Carbon , Cycloalkyl Halides , Carbanions , Nitroalkanes , Nitrogen Nucleophiles , Phosphorus Nucleophiles , Oxygen
Journal title :
INORGANIC CHEMISTRY
Journal title :
INORGANIC CHEMISTRY