Title of article :
Spectroscopic and Computational Studies of a Ni+ -CO Model Complex: Implications for the Acetyl-CoA Synthase Catalytic Mechanism
Author/Authors :
Fujita، Koyu نويسنده , , Riordan، Charles G. نويسنده , , Craft، Jennifer L. نويسنده , , Mandimutsira، Beaven S. نويسنده , , Brunold، Thomas C. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The coordination chemistry of the oxadiazole-containing rigid bidentate ligands 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (L2) and 2,5-bis(4-aminophenyl)-1,3,4-oxadiazole (L3) with inorganic Ag(l) salts has been investigated. Four new coordination polymers were prepared by solution reactions and fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. {[Ag(L2)]SO3CF3}n (1) (triclinic, PI; a = 10.1231(7) A, b = 13.9340-...
Keywords :
Aliphatic Substrates , Carbonylation , EWG , Neopentyl , Nitroalkanes , Carbanions , Phosphorus Nucleophiles , Nitrobenzyl , sp2 Carbons , Cumyl , Oxygen , sp3 Carbons , Heterocyclic Analogues , Photostimulated Reactions , Geminal Dihalides , Radicals Intermediates , Trihalides , stereochemistry , Triorganylstannyl , Regiochemistry , Alicyclic Aliphatic Substrates , Sulfur Nucleophiles , Nitrogen Nucleophiles , (alpha)Carbon , Cycloalkyl Halides
Journal title :
INORGANIC CHEMISTRY
Journal title :
INORGANIC CHEMISTRY
