• Title of article

    An Unprecedented Oxidative Migration of a Methyl Group from 2-(2,6-Dimethylphenylazo)-4-methylphenol Mediated by Ruthenium and Osmium

  • Author/Authors

    Lee، Gene-Hsiang نويسنده , , Bhattacharya، Samaresh نويسنده , , Peng، Shie-Ming نويسنده , , Acharyya، Rama نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    -7377
  • From page
    7378
  • To page
    0
  • Abstract
    An unprecedented chemical transformation of 2-(2ʹ,6ʹ-dimethylphenylazo)-4-methylphenol has been observed upon its reaction with [M (PPh3)3X2] (M = Ru, Os; X = Cl, Br) whereby one methyl group from the phenyl ring of the arylazo fragment migrates to the metal center via oxidation to CO.
  • Keywords
    molecular processes , molecular data , ISM: molecules
  • Journal title
    INORGANIC CHEMISTRY
  • Serial Year
    2003
  • Journal title
    INORGANIC CHEMISTRY
  • Record number

    67122